Choosing storage enclosures
Acid-free, lignin-free and buffered are three different claims, and one of them is wrong for protein material.
Updated 14 August 2026
An enclosure does four jobs at once: it buffers humidity, excludes light completely, forms a barrier to dust and insects, and lets the object be moved without being touched. It also, if specified badly, becomes a source of acid sitting in contact with the object for decades.
The difficulty is that the vocabulary used to sell enclosures is looser than the vocabulary needed to specify them.
Three claims that are not the same
Acid-free describes pH at the time of manufacture. It is a snapshot. A board made from wood pulp containing lignin can be acid-free when it leaves the factory and measurably acidic ten years later, because lignin degrades and generates acid as it does.
Lignin-free describes composition, and it is the property that predicts long-term behaviour. This is the more meaningful claim of the two.
Buffered means the board contains an alkaline reserve, typically calcium carbonate, which neutralises acid as it forms, whether from the board itself or migrating from the object. This is a genuine benefit for paper and other plant-fibre material, and it is a problem for protein material.
The last point is the one most often got wrong. Wool, silk, leather, parchment, feather and hair are damaged by alkaline conditions, and some dyes shift colour in an alkaline environment. Several photographic processes have the same issue. For these, the correct specification is unbuffered, neutral pH.
Plastics
For plastic enclosures the question is simply which polymer. Polyester, polyethylene and polypropylene are stable, chemically inert and the established choices. PVC is not: it contains plasticisers that migrate and it releases acidic degradation products.
Trade names do not answer the question. A supplier who cannot say which polymer a sleeve is made from is a supplier to avoid.
One general caution about plastic enclosures: they are impermeable, so anything sealed inside with moisture stays with it. For material that is not fully dry, or in an environment where the object could be brought in cold and warmed, a permeable paper enclosure is safer.
Photographs need their own test
Photographic emulsions react with enclosure materials in ways that the general paper tests do not predict. The relevant assessment is the Photographic Activity Test, which exposes the enclosure material to a detector under accelerated conditions and looks for image fading and staining.
Enclosures for photographic material should state a PAT pass. Absence of any statement should be read as untested rather than as passed. Photographs covers the wider question, including which processes need unbuffered enclosures.
Practical fit and construction
Beyond chemistry, the mundane things decide whether an enclosure protects anything.
A box that is too large lets the contents shift; one that is too small forces the object in. Both cause more damage than the chemistry ever will. Drop-front and clamshell designs allow an object to be lifted out without being dragged over a lip, which matters a great deal for anything flat or fragile.
Metal staples and fasteners corrode and stain, and adhesives vary enormously in quality. A box with well-made corner construction and no metal in contact with the interior is worth the difference.
Size to what the store can actually hold and to what a person can lift down safely from the shelf it will live on. Shelving and racking covers the other half of that decision.
Tissue and interleaving
Acid-free tissue is the general-purpose padding, interleaving and wrapping material. Unbuffered is the safer default in a mixed collection, because it is acceptable everywhere while buffered tissue is not.
Use it to support rather than to fill. Rolled tissue supports a fold so a textile is not creased; crumpled tissue packed tight around an object exerts pressure and can distort it.
What to ask a supplier
The specification questions that separate a defensible purchase from an adjective. We do not test materials; these are the questions the data sheet must answer.
- 01 · Chemistry
Stated pH, with the test method
Acid-free describes pH at manufacture. Without a method and a figure it is an adjective.
Speaks for it
- A stated cold extract pH with a reference standard is a real specification
Worth weighing
- Acid-free alone says nothing about how the board will behave in twenty years
- 02 · Longevity
Lignin content
Lignin degrades and generates acid over time, so a board can be acid-free today and acidic later.
Speaks for it
- Lignin-free is the property that predicts long-term behaviour
Worth weighing
- Cheap boards are frequently acid-free but not lignin-free
- 03 · Buffering
Alkaline reserve, and whether you want it
A calcium carbonate reserve neutralises acid as it forms. Right for paper and plant fibre, wrong for wool, silk and some photographic processes.
Speaks for it
- Buffered board extends the life of acidic paper considerably
Worth weighing
- Buffered enclosures can damage protein material and some dyes
- 04 · Photographs
Photographic Activity Test result
The specific test for enclosures in contact with photographic material.
Speaks for it
- A stated PAT pass is the only meaningful assurance for photographs
Worth weighing
- Absence of a PAT statement usually means it has not been tested
- 05 · Plastics
Named polymer, for plastic enclosures
Polyester, polyethylene and polypropylene are the safe choices. PVC is not.
Speaks for it
- A named polymer is verifiable; a trade name is not
Worth weighing
- Clear plastic sleeves of unstated composition are a common and avoidable risk
Frequently asked questions
- What does archival mean?
- Nothing defined. It is a marketing term with no standard behind it. The properties that matter are pH, lignin content, alkaline reserve and, for photographs, a PAT result, and a supplier who cannot state them is selling an adjective.
- When is buffered board the wrong choice?
- For protein material, meaning wool, silk, leather, parchment, feather and hair, and for some dyes and photographic processes. In these cases an unbuffered, neutral pH enclosure is correct.
- Is unbleached tissue better than white?
- Not inherently. What matters is the pH, lignin content and whether it is buffered, not the colour. Unbuffered acid-free tissue is the general-purpose choice for mixed collections.
Related reading
Textiles
The most light-sensitive material in most collections and the first thing clothes moths find. Two risks that dominate everything else.
Photographs
The material group most likely to be quietly destroying itself, and the one where cold storage changes the answer most.
Display cases
A case is a climate chamber, a pollutant chamber and a security enclosure at once. The specification decides which one dominates.
Shelving and racking
Material choice keeps acids away from the objects. Layout keeps hands away from them.
Handling and gloves
Cotton gloves are no longer the default. What replaced them, and the handling habits that matter more than any glove.
Transport and crates
Shock, vibration and a climate that changes faster than anywhere else. What a real packing case does about each.